Binding energy and mass defect
The mass of a nucleus is always less than the total mass of its separate protons and neutrons. This difference is the mass defect \(\Delta m\). By \(E = mc^2\), it corresponds to the binding energy: the energy needed to pull the nucleus completely apart into free nucleons (or the energy released when it forms).
In atomic mass units, \(1\ \text{u}\) is equivalent to \(931.5\ \text{MeV}\), which makes the conversion quick.
The binding energy per nucleon measures stability. Plotted against \(A\), it rises steeply for light nuclei, peaks near iron-56 at about \(8.8\ \text{MeV}\), then falls slowly for heavy nuclei. As a result:
- Fusion of light nuclei moves toward the peak and releases energy.
- Fission of heavy nuclei also moves toward the peak and releases energy.
Types of decay
Unstable nuclei decay randomly and spontaneously, emitting radiation:
| Decay | Particle | Change to nucleus | Ionising | Stopped by |
|---|---|---|---|---|
| Alpha (\(\alpha\)) | \(^{4}_{2}\text{He}\) nucleus | \(A - 4\), \(Z - 2\) | strongly | paper or a few cm of air |
| Beta-minus (\(\beta^-\)) | electron + antineutrino | \(Z + 1\), \(A\) same | moderately | a few mm of aluminium |
| Beta-plus (\(\beta^+\)) | positron + neutrino | \(Z - 1\), \(A\) same | moderately | a few mm of aluminium |
| Gamma (\(\gamma\)) | high-energy photon | no change in \(A\) or \(Z\) | weakly | reduced by thick lead or concrete |
In \(\beta^-\) decay a neutron turns into a proton; in \(\beta^+\) a proton turns into a neutron. In every nuclear equation both \(A\) and \(Z\) must balance on each side.
Neutrinos
Beta particles from one nuclide come out with a continuous range of kinetic energies, up to a maximum. If only two particles were produced, energy and momentum conservation would fix a single value. The spread showed that a third, nearly massless, uncharged particle shares the energy: the neutrino (or antineutrino). Alpha particles, by contrast, come out with discrete energies.
Half-life and activity
Decay is random: you cannot predict when a given nucleus will decay, only the probability. With huge numbers of nuclei, the pattern is smooth.
- Activity \(A\) is the number of decays per second, measured in becquerels (Bq).
- Half-life \(T_{1/2}\) is the time for the number of undecayed nuclei, or the activity, to halve.
After \(n\) half-lives the fraction remaining is \(\left(\frac{1}{2}\right)^n\).
Background radiation and safety
Detectors always record a background count from rocks, radon gas, cosmic rays, food and medical sources. Measure it first and subtract it from every reading. Protect yourself by keeping exposure short, distance large and using shielding.
Decay constant and exponential decay (HL)
The decay constant \(\lambda\) is the probability per unit time that a nucleus decays. Then:
\[N = N_0 e^{-\lambda t}, \quad A = \lambda N = A_0 e^{-\lambda t}, \quad T_{1/2} = \frac{\ln 2}{\lambda}\]
A graph of \(\ln A\) against \(t\) is a straight line with gradient \(-\lambda\).
Nuclear energy levels (HL)
Alpha particles and gamma photons from a given nuclide have discrete energies. This shows that nuclei, like atoms, have quantised energy levels. Gamma emission often follows alpha or beta decay as the daughter nucleus drops from an excited state to its ground state. The very short range of the strong force is supported by the constant nuclear density and the deviations in scattering experiments.
Worked example 1: binding energy of helium-4
Data: proton \(1.007276\ \text{u}\), neutron \(1.008665\ \text{u}\), helium-4 nucleus \(4.001506\ \text{u}\).
- Separate nucleons: \(2(1.007276) + 2(1.008665) = 4.031882\ \text{u}\)
- Mass defect: \(4.031882 - 4.001506 = 0.030376\ \text{u}\)
- Binding energy: \(0.030376 \times 931.5 = 28.3\ \text{MeV}\)
- Per nucleon: \(\frac{28.3}{4} = 7.07\ \text{MeV}\)
Worked example 2: activity after a non-whole number of half-lives (HL)
A source has activity \(800\ \text{Bq}\) and half-life \(6.0\ \text{h}\). Find its activity after \(15\ \text{h}\).
- \(15\ \text{h}\) is \(2.5\) half-lives.
- \(A = 800 \times \left(\frac{1}{2}\right)^{2.5} = 800 \times 0.177 = 1.4 \times 10^2\ \text{Bq}\) (2 s.f.)
Common mistakes
- Saying binding energy is energy "stored" in the nucleus that it gives out; it is the energy needed to separate it.
- Forgetting the antineutrino in \(\beta^-\) equations or the neutrino in \(\beta^+\).
- Not subtracting background before calculating half-life.
- Thinking a sample is gone after two half-lives; a quarter remains.
- Using hours in \(\lambda\) but seconds in activity calculations.
Exam tips
- Balance top and bottom numbers explicitly when completing a decay equation.
- When reading half-life from a graph, use several halvings and average them.
- Use the \(\left(\frac{1}{2}\right)^n\) shortcut when \(n\) is a whole number; use \(e^{-\lambda t}\) otherwise.
- Keep all six decimal places in mass-defect sums; rounding early can wipe out the answer.