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Physics

E.3 Radioactive decay

Why some nuclei are unstable, how mass defect gives binding energy, how alpha, beta and gamma decays change a nucleus, and how half-life and activity describe decay; at HL, the decay constant, exponential law and nuclear energy levels. Study guide, 7 practice questions with markschemes and 8 flashcards. Free.

isotopes and binding energy · mass defect and binding energy per nucleon · alpha, beta and gamma decay · neutrinos · half-life and activity · background radiation and safety · (HL) decay constant and exponential decay law · (HL) nuclear energy levels and the strong force evidence

Practise all 7 questions Study 8 flashcards

Study guide

Binding energy and mass defect

The mass of a nucleus is always less than the total mass of its separate protons and neutrons. This difference is the mass defect \(\Delta m\). By \(E = mc^2\), it corresponds to the binding energy: the energy needed to pull the nucleus completely apart into free nucleons (or the energy released when it forms).

In atomic mass units, \(1\ \text{u}\) is equivalent to \(931.5\ \text{MeV}\), which makes the conversion quick.

The binding energy per nucleon measures stability. Plotted against \(A\), it rises steeply for light nuclei, peaks near iron-56 at about \(8.8\ \text{MeV}\), then falls slowly for heavy nuclei. As a result:

Types of decay

Unstable nuclei decay randomly and spontaneously, emitting radiation:

DecayParticleChange to nucleusIonisingStopped by
Alpha (\(\alpha\))\(^{4}_{2}\text{He}\) nucleus\(A - 4\), \(Z - 2\)stronglypaper or a few cm of air
Beta-minus (\(\beta^-\))electron + antineutrino\(Z + 1\), \(A\) samemoderatelya few mm of aluminium
Beta-plus (\(\beta^+\))positron + neutrino\(Z - 1\), \(A\) samemoderatelya few mm of aluminium
Gamma (\(\gamma\))high-energy photonno change in \(A\) or \(Z\)weaklyreduced by thick lead or concrete

In \(\beta^-\) decay a neutron turns into a proton; in \(\beta^+\) a proton turns into a neutron. In every nuclear equation both \(A\) and \(Z\) must balance on each side.

Neutrinos

Beta particles from one nuclide come out with a continuous range of kinetic energies, up to a maximum. If only two particles were produced, energy and momentum conservation would fix a single value. The spread showed that a third, nearly massless, uncharged particle shares the energy: the neutrino (or antineutrino). Alpha particles, by contrast, come out with discrete energies.

Half-life and activity

Decay is random: you cannot predict when a given nucleus will decay, only the probability. With huge numbers of nuclei, the pattern is smooth.

After \(n\) half-lives the fraction remaining is \(\left(\frac{1}{2}\right)^n\).

Background radiation and safety

Detectors always record a background count from rocks, radon gas, cosmic rays, food and medical sources. Measure it first and subtract it from every reading. Protect yourself by keeping exposure short, distance large and using shielding.

Decay constant and exponential decay (HL)

The decay constant \(\lambda\) is the probability per unit time that a nucleus decays. Then:

\[N = N_0 e^{-\lambda t}, \quad A = \lambda N = A_0 e^{-\lambda t}, \quad T_{1/2} = \frac{\ln 2}{\lambda}\]

A graph of \(\ln A\) against \(t\) is a straight line with gradient \(-\lambda\).

Nuclear energy levels (HL)

Alpha particles and gamma photons from a given nuclide have discrete energies. This shows that nuclei, like atoms, have quantised energy levels. Gamma emission often follows alpha or beta decay as the daughter nucleus drops from an excited state to its ground state. The very short range of the strong force is supported by the constant nuclear density and the deviations in scattering experiments.

Worked example 1: binding energy of helium-4

Data: proton \(1.007276\ \text{u}\), neutron \(1.008665\ \text{u}\), helium-4 nucleus \(4.001506\ \text{u}\).

Worked example 2: activity after a non-whole number of half-lives (HL)

A source has activity \(800\ \text{Bq}\) and half-life \(6.0\ \text{h}\). Find its activity after \(15\ \text{h}\).

Common mistakes

Exam tips

Cheat sheet

EquationSymbolsUnits
\(\Delta m = Zm_p + (A-Z)m_n - m_{\text{nucleus}}\)\(m_p\), \(m_n\) proton and neutron massesu or kg
\(E = \Delta m c^2\)\(c = 3.00 \times 10^8\) m s\(^{-1}\)J
\(1\ \text{u} = 931.5\ \text{MeV}\,c^{-2}\)atomic mass unitMeV
\(N = N_0\left(\frac{1}{2}\right)^{n}\)\(n = t/T_{1/2}\) half-lives elapsednone
(HL) \(N = N_0 e^{-\lambda t}\)\(\lambda\) decay constantnone
(HL) \(A = \lambda N = A_0 e^{-\lambda t}\)\(A\) activityBq
(HL) \(T_{1/2} = \frac{\ln 2}{\lambda}\)\(T_{1/2}\) half-lifes

Key definitions

Mass defect

The difference between the total mass of the separate nucleons and the mass of the nucleus they form.

Binding energy

The minimum energy required to separate a nucleus completely into its individual protons and neutrons.

Binding energy per nucleon

The binding energy of a nucleus divided by its nucleon number; higher values indicate more stable nuclei.

Activity

The number of nuclei in a sample that decay per second, measured in becquerels (Bq).

Half-life

The time taken for half of the undecayed nuclei in a sample, or the activity, to fall to half its value.

Background radiation

Ionising radiation always present in the environment from natural and artificial sources, independent of the source being studied.

Neutrino

A neutral particle with almost no mass emitted in beta decay, carrying away part of the energy released.

Decay constant (HL)

The probability per unit time that an individual nucleus will decay, in s^-1.

Random decay

Decay that cannot be predicted for any single nucleus and is unaffected by temperature, pressure or chemical state.

Practice questions

SLPaper 1AStandard

Question 1

(a) [1]

Carbon-14, \(^{14}_{6}\text{C}\), undergoes beta-minus decay. Which are the products?

  • A. \(^{14}_{7}\text{N}\), an electron and an antineutrino
  • B. \(^{14}_{5}\text{B}\), a positron and a neutrino
  • C. \(^{10}_{4}\text{Be}\) and an alpha particle
  • D. \(^{14}_{7}\text{N}\), an electron and a neutrino
Markscheme
  • 1 A. In beta-minus decay a neutron becomes a proton, so \(Z\) rises by 1 and \(A\) is unchanged; an electron and an electron antineutrino are emitted.
SLPaper 1AStandard

Question 2

(a) [1]

The activity of a radioactive sample falls from \(800\ \text{Bq}\) to \(50\ \text{Bq}\) in \(24\ \text{h}\). What is the half-life?

  • A. 3 h
  • B. 6 h
  • C. 8 h
  • D. 12 h
Markscheme
  • 1 B. \(800 \to 400 \to 200 \to 100 \to 50\) is 4 half-lives in 24 h, so each is 6 h.
SLPaper 1AStandard

Question 3

(a) [1]

The kinetic energy of electrons emitted in beta-minus decay of a given nuclide varies continuously from zero to a maximum value. What does this suggest?

  • A. Energy is not conserved in beta decay
  • B. A third particle carries away part of the energy released
  • C. The nucleus has no discrete energy levels
  • D. The electrons lose energy in the source material
Markscheme
  • 1 B. The decay energy is fixed, so a continuous electron spectrum means the energy is shared with another particle: the antineutrino.

Key facts

What are isotopes?

Nuclides with the same number of protons but different numbers of neutrons.

Define mass defect and binding energy.

Mass defect: total mass of separate nucleons minus mass of the nucleus. Binding energy: energy needed to separate a nucleus into its nucleons, \(E = \Delta m c^2\).

Which nuclide has (about) the highest binding energy per nucleon?

Iron-56 (and nickel-62), about 8.8 MeV per nucleon. Fusion of lighter and fission of heavier nuclei both release energy.

Compare the penetrating power of alpha, beta and gamma radiation.

Alpha: stopped by paper or a few cm of air. Beta: stopped by a few mm of aluminium. Gamma: reduced but not fully stopped by several cm of lead.

What changes in beta-minus decay?

A neutron changes into a proton: \(Z\) increases by 1, \(A\) unchanged; an electron and an electron antineutrino are emitted.

Define half-life.

The time for half of the undecayed nuclei of a nuclide to decay, or for the activity to fall to half.